L-Malic acid
The acid plants make right beside their photosynthetic machinery, and a partner of potassium in balancing charge. Nik's point is to leave it to the plant.
Structure data: PubChem open chemistry database
Tea and Terps · Episode 3
Over a giant-leaved Bing Dao pu'er, Nik and Travis take the community's questions: why some acids stay out of a formula, why nitrate is the expensive form of nitrogen, and how your soil and your air move water through a plant.
The cup
Pu'er comes from Yunnan in China's far southwest, and it comes in two kinds. Sheng, or raw, pu'er is made like a green tea and sun dried, then left to age slowly; shu, or ripe, pu'er is piled and fermented for a month or two, which makes it dark and smooth from the start. Nik's cup is sheng: Moss Island 2018, loose maocha from Bing Dao village in Lincang.
Bing Dao means ice island, and it has been one of the most famous and expensive pu'er villages since the mid 2000s. Its trees are a large-leaf variety, and the leaves are so big they barely fit the pot. Nik brewed them with boiling water for more than ten minutes in total, and they were only just beginning to soften.
What Nik noticed
Special notes
Loose maocha, rather than a pressed cake.
| Compared | Sheng, or raw | Shu, or ripe |
|---|---|---|
| How it is made | Withered, pan-fired, rolled and sun dried | Piled and fermented for weeks, then dried |
| The cup | Gold to amber | Close to black |
| When young | Bright and often fiercely bitter | Smooth, earthy and never bitter |
| With age | Bitterness softens over years | Ready to drink sooner |
Nik's notes from the session. The leaves were still plump after six or seven steeps.
Chapter by chapter
Press any time to play the episode from that moment. While it plays, the chapter you are in lights up.
Terroir
A listener asked what elevation Bing Dao grows at and what day-night swings do to aroma. Nik's answer: tea from high, cold places has to cope with big swings in temperature and humidity, and it grows slowly. The compounds a leaf makes to cope build up in a smaller, slower-growing leaf, so the flavor ends up more concentrated.
Most plants can only endure the cold, but a few make their own heat. Later in the episode Nik describes skunk cabbage, which burns its stored sugars fast enough to heat its flowers and melt its way up through snow. For the rest, the response to hard conditions shows up in their chemistry, and that is part of what a tea drinker tastes in a mountain tea.
A general pattern in mountain teas; how much it explains in any one garden depends on the cultivar and the year.
Organic acids
One question went straight to the formulas. Rooted Leaf's carry acetates and citrates, and the listener had spotted a pattern: acetate has one acid group, citrate three, so why skip malate, the one with two? Nik's answer is that malate sits right beside the photosynthetic machinery. Plants make it in the chloroplasts and the cell around them, and they use it, together with potassium, to balance charge and keep photosynthesis running smoothly.
Because the plant already runs that balance so precisely, Nik chose not to add malate from outside and risk disturbing it. Acetate and citrate are different: they are carbon skeletons a plant can take in and route into its own metabolism, and citrate can hold metals such as iron and calcium in solution on the way.
Malate is a very specific flavor of organic acids that sit very close to the photosynthetic machinery.
Nik
| Acid | Where the plant meets it | Nik's choice |
|---|---|---|
| Malate | Made beside the photosynthetic engine, paired with potassium | Left to the plant |
| Citrate | Central to respiration; holds metals in solution | Used |
| Acetate | The smallest carbon skeleton, straight into metabolism | Used |
Nitrogen
Some growers treat nitrate as a dirty word. Nik does not. Nitrate is the oxidized, settled form nitrogen falls into over time, living soil makes it, and the common nitrate salts are fairly benign. The catch is what it costs a plant to use it.
Before nitrate can become part of an amino acid it has to take on eight electrons: two to become nitrite, six more to become ammonium, and only then can it be fixed onto a carbon skeleton. Ammonium and amino acids skip most of that cost. Nik's advice is to look past the total nitrogen in a feed to the ratio of ammoniacal to nitrate nitrogen, because the energy a plant spends reducing nitrate is energy it cannot spend elsewhere. Too much nitrate late in flower, he and Travis agree, tends to show up as stretch, airy tops and leafy flowers.
It's an energy threshold for the plants.
Nik
Eight electrons in all, supplied by the plant's own energy. Ammonium enters at the third step and amino acids at the last.
Why plants make what they make
It is easy to talk about terpenes, flavonoids and cannabinoids as if plants made them for us. Nik's reminder near the end of the episode is that these compounds are something else first. They protect the plant from light and heat, deter what wants to eat it, attract what it needs, and help it hold its balance through cold nights and dry days.
That matters for a grower, because it means a plant spends its energy on these compounds when its own situation calls for them. Travis puts it plainly: self-preservation is the first law of nature. The flavor in the jar or the cup comes from compounds the plant made in response to the conditions it lived through.
Real structures
Five molecules from the episode, rendered from real PubChem geometry rather than drawn. Pick one to read why it matters, then turn it in three dimensions.
The acid plants make right beside their photosynthetic machinery, and a partner of potassium in balancing charge. Nik's point is to leave it to the plant.
Structure data: PubChem open chemistry database
An acid of respiration that can hold metals such as iron and calcium in solution, one of the organic acids that can carry a mineral into a plant.
Structure data: PubChem open chemistry database
The smallest organic acid in the conversation. As acetate it is a two-carbon skeleton that feeds straight into a plant's metabolism.
Structure data: PubChem open chemistry database
The first amino acid ammonium is built into. Nitrate has to be reduced all the way before it can get here; ammonium and amino acids skip most of that cost.
Structure data: PubChem open chemistry database
The alkaloid that makes tea stimulating, and a plant defense first: bitter, and harmful to many of the insects that try to eat the leaf.
Structure data: PubChem open chemistry database
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Water
Travis closed with a question from a friend whose room had drifted off the usual VPD targets. Nik's answer looked past the air to the whole soil-plant-air continuum. Water moves through a plant because of a difference in pressure: the soil pushes and the dry air pulls, and both are measured in the same units, kilopascals.
So the target for the air depends on the soil. If your mix holds a lot of water, run a drier VPD so the plant can pull water through more freely; if your room is humid and hard to dry, choose a faster-draining medium such as coco that cycles between wet and dry more quickly. Chasing a VPD chart without looking at the root zone misses half of the system.
What you wanna do at that point is run a drier VPD
Nik
| If | Then | Why |
|---|---|---|
| Your mix holds water well | Run a drier VPD | The air can pull what the soil pushes |
| Your room stays humid | Grow in a faster-draining medium | The root zone cycles wet and dry faster |
Moments worth rewinding
Moments from the clip archive. Each one plays the full episode from where it starts, and the short plays on its own.
Raw pu'er is made like a green tea and aged slowly; ripe pu'er is fermented in piles for weeks before it is dried.
A 2014 cake and the 2018 loose maocha come from the same village; pressing changes how the leaf looks and ages.
Nik brews Bing Dao in Dahongpao clay, an iron-rich red clay from the Yixing family.
Cooler gardens and slower growth leave more of the leaf's protective and aromatic compounds in every leaf.
He filters his water to zero, then judges for himself how minerals change each tea. There is no single right water.
Late in the session the camphor and root beer give way to peaches and apricots, and the leaves stay plump.
Stretch, airy tops and leafy flowers, in Nik and Travis's experience.
Skunk cabbage burns its stored sugars fast enough to warm its flowers well above the freezing air.
Keep listening
Episode 3 is the community's episode, and Episode 4 follows the B vitamins into the plant's machinery.
Episode 2 · The one beforeEnergy and WuyiEnergy, and what it lets a plant build, over a Wuyi rock oolong.
Episode 4 · The one afterB Vitamins and BulangB vitamins as the cofactors that let a plant build its terpenes, pigments and cannabinoids.
Episode 1 · Where it beganCarbon and Fenghuang OolongCarbon, the element plants are built from, over a cup of Phoenix oolong.