ATP
The molecule cells use to carry energy. Light's energy, captured as a proton gradient across a membrane, is stored in ATP's phosphate bonds and spent wherever the plant does work.
Structure data: PubChem open chemistry database
Tea and Terps · Episode 2
Nik and Travis open a nine-year-old rock tea from Wuyi, the mountain whose Bohea filled the chests of the Boston Tea Party, and Nik lays out the forgotten physics of agriculture: three equations that describe the board plant nutrition is played on.
The cup
Rock tea, or yancha, comes from the cliffs and gorges of Wuyi Mountain in Fujian, and Nik ranks it with Phoenix oolong as a tea in a league of its own. Lily Eccentric is a Qi Lan from Hui Yuan Keng, a long, deep ravine in the mountain's core where some trees see only a couple of hours of sun a day and mist keeps everything damp and mossy.
The packet was from 2017. A well-made rock tea does not go stale, Nik explains; it concentrates and clarifies, and this one still filled the room with flowers, spice and wet stone nine years on. It is lightly roasted, the opposite end of the spectrum from the full-roast rock teas he saves for winter.
What Nik noticed
Special notes
An aged Qi Lan from Hui Yuan Keng, within Wuyi’s core rock-tea country.
Nik brewed this tea gongfu style: a lot of leaf, a little water and very short steeps, each one peeling back a different layer of the roast.
Chapter by chapter
Press any time to play the episode from that moment. While it plays, the chapter you are in lights up.
History
In May 1773 Parliament passed the Tea Act, giving the East India Company a monopoly on selling tea to the colonies, which still paid a duty of three pence a pound with no say in Parliament. In December, the Sons of Liberty boarded three ships in Boston Harbor and dumped 342 chests of tea overboard. Of those, 240 were labeled Bohea, the old Western name for Wuyi tea.
Nik doubts that Boston was drinking anything like the rock tea in his cup. Oolong making was still young in Wuyi, the region was experimenting with black tea, and demand already far outran what the cliffs could grow, so stream-side teas from much nearer the ports were made to look like cliff teas. An old poem by a Qing dynasty monk, the Song of Wuyi Tea, describes exactly that.
Last night 3 cargoes of Bohea tea were emptied into the sea. This is the most magnificent movement of all.
John Adams, diary, 17 December 1773, read by Nik
342 chests in all, destroyed on 16 December 1773.
Terroir
Wuyi Mountain is a UNESCO World Heritage Site, a maze of peaks, cliffs and gorges, and the most prized rock teas come from a small core of it. Lily Eccentric grows in one of those gorges, Hui Yuan Keng, where, as Nik describes it, mist clings to the cliffs and slowly carries water and dissolved minerals down to slow-growing, moss-covered bushes.
Chinese tea drinkers sum up what that place gives the cup in four words: rock bone, flower fragrance, yan gu hua xiang. Nik drank rock tea every day for more than a year before he felt he had an entry-level understanding of it. The best ones, he says, taste of exactly where they grew, whether a sunny hilltop or a damp pit with an hour or two of light.
You could spend a year drinking nothing but rock teas day after day and still not fully understand what those 4 words mean.
Nik
| In the cup | Lily Eccentric | Full-roast rock tea |
|---|---|---|
| Charcoal roast | Less: Light | More: Deep |
| Liquor | Gold | Copper, bronze or red |
| When Nik drinks it | Spring and summer | Autumn and winter |
| What leads | Flowers, moss and wet rock | Roast, wood and spice |
Real structures
Five molecules from the episode, rendered from real PubChem geometry rather than drawn. Pick one to read why it matters, then turn it in three dimensions.
The molecule cells use to carry energy. Light's energy, captured as a proton gradient across a membrane, is stored in ATP's phosphate bonds and spent wherever the plant does work.
Structure data: PubChem open chemistry database
The first product of the phenylpropanoid pathway, made when an enzyme strips the nitrogen from phenylalanine. Its relative cinnamaldehyde is the smell of cinnamon, which is why Nik wonders about it in aged tea.
Structure data: PubChem open chemistry database
An anthocyanin, one of the pieces plants make to screen light before it reaches the chloroplasts.
Structure data: PubChem open chemistry database
An organic acid plants make and release. Its acid groups can hold metal ions in solution, one of the chelating pieces Nik describes, freeing nutrients that would otherwise be stuck on the board.
Structure data: PubChem open chemistry database
Tea's main catechin. In an oolong, partial oxidation turns some of it into the reddish compounds of the leaf's bruised edges.
Structure data: PubChem open chemistry database
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A short history
The way we think about fertilizer was built between the 1820s and 1913: Carl Sprengel's mineral theory, popularized by Justus von Liebig, superphosphate, the pH scale and finally the Haber-Bosch process for making ammonia. Nik calls it the NPK model, and he means it as a compliment. It taught the world that deficiencies limit growth and how to correct them.
In the twentieth century, physics took humanity from gunpowder to the atom and from horses to jet engines, yet fertilizer, in Nik's view, barely changed. Quantum physics, thermodynamics and electrochemistry all describe how plants live, and his argument is that they never fully made it into how fertilizer is designed.
I don't think there's anything wrong with the NPK model, but it is incomplete.
Nik
The chessboard
Nik's way into the physics is a chessboard. Nitrogen, phosphorus, potassium and the rest are the pieces, each with its own moves. The squares are not neutral: properties such as pH and cation exchange capacity change how a piece behaves when it lands, and can lock it up so the plant cannot move it again.
Plants also make pieces of their own and put them on the board: chelators that free stuck nutrients, and pigments and antioxidants that keep the chlorophyll in good positions. Beneath all of it are the rules, and for Nik those are three equations. The NPK model asked which pieces we can move; he wants to ask how the board itself can be worked with.
These 3 equations are the board itself and the rules of the game.
Nik
Light, work and charge
Planck's relation gives the energy in a single photon. Nik works it out for red light at 680 nanometers, the color photosystem II's reaction center is tuned to: about 2.9 times ten to the minus nineteen joules, or 1.8 electronvolts. A blue photon carries more, so a blue-excited chlorophyll first sheds the surplus as heat, within a fraction of a trillionth of a second, before its excitation is passed on.
Gibbs free energy describes the landscape of possible work: which reactions can run, and how much useful work they can do. Nernst's equation describes how charge and concentration set a voltage, the language of membrane potentials, proton gradients and redox. Joined, they say the work available from moving charge equals the charge moved times the voltage, the idea Nik keeps returning to. Nernst, by the way, was so eminent in 1910 that his trip to Zurich to meet a little-known physicist helped make that physicist famous: Albert Einstein.
From Planck's relation, energy equals Planck's constant times the light's frequency. Photosystem II runs on the red photon; bluer light brings more energy than it needs.
| Equation | What it answers | In a leaf |
|---|---|---|
| Planck | How much energy light brings | Each photon's energy, by color |
| Gibbs | What work is possible | Which reactions can run, and how far |
| Nernst | How charge behaves | Membrane voltages and proton gradients |
Moments worth rewinding
Moments from the clip archive. Each one plays the full episode from where it starts, and the shorts play on their own.
The core of Wuyi is tiny and the good leaf is picked once a year, so demand has outrun supply for centuries.
A well-made rock tea holds its roast for years, and makers may roast it again a decade or more later.
A 1983 oolong tasted of cinnamon raisin bagels. Nik's hunch is that age peels tea back toward simpler molecules such as cinnamic acid; the chemistry of aged aroma is still being worked out.
Charcoal firing over local woods, guava and lychee among them for Phoenix oolong, leaves its mark in the cup.
The reaction center is tuned to 680 nanometers; a blue photon's extra energy is shed as heat before its excitation moves on.
In 1910 the great Walther Nernst traveled to Zurich to meet a little-known physicist named Albert Einstein.
A pigment needs no metabolism to screen light: the moment a photon meets an anthocyanin, it can be absorbed.
Amazonian dark earths, built up with charcoal and pottery shards, have stayed fertile for centuries.
Keep listening
Episode 2 widens the carbon story of Episode 1 into energy, and Episode 3 brings it back to the grow.
Episode 1 · The one beforeCarbon and Fenghuang OolongCarbon, the element plants are built from, over a cup of Phoenix oolong.
Episode 3 · The one afterQ&A and Bing DaoListener questions and how Rooted Leaf works, over a Bing Dao pu'er.
Episode 5Pigments and GyokuroPigments and gyokuro: the colors of a leaf, from chlorophyll to anthocyanins.